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UreaKnowHow.com introduces a Group Discount for its 5-Day Training Program for Urea Engineers 23-27 July 2012 in Dubai.
We recommend to use a vacuum based leak detection system for several important reasons:
Reason #1: No risk of liner bulging (refer to FAQ 6)
Reason #2: Direct coverage of the complete carbon steel surface of a compartment (refer to FAQ 7)
Reason #3: A vacuum system is less prone to clogging (refer to FAQ 9)
Reason #4: A vacuum system does not restrict the leaking flow and does not built-up pressure or introduces risks for backflow (refer to FAQ 10)
Reason #5: A vacuum system also works when there is only one leak detection hole in a liner compartment (refer to FAQ 11)
Reason #6: A vacuum system also works when there are clogged grooves or no grooves (refer to FAQ 12)
Reason #7 is: A pressurised system requires a dedicated ammonia analyser for each high pressure equipment item whereas a vacuum system needs only one ammonia analyser for all high pressure equipment items to realise the same reliability.
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High pressure urea equipment consists of a carbon steel pressure bearing wall, which is protected against corrosion by a protective layer. This protective layer is typically an overlay welding or a loose liner. Any leak in a loose liner will lead to a dangerous situation in that a large surface of the carbon steel pressure bearing wall underneath the leaking loose liner compartment will be exposed to the extremely corrosive ammonium carbamate. Experience has shown that ammonium carbamate can corrode carbon steels with very high corrosion rates up to 1,000 mm (40 inch) per year.
When talking about active leak detection systems, one can distinguish a pressurized system, in which an inert carrier gas stream flows through the leak detection circuits and a vacuum based system, where one pulls vacuum pressure behind the liner (refer to FAQ 5)
It is a real challenge to avoid clogging as urea easily crystallises at any temperature even above its melting point due to its polymerisation behaviour forming biuret, triuret etc. with high melting points. This is the main reason that we strongly recommend to upgrade any passive leak detection system (FAQ 3).
We recommend to use a vacuum based leak detection system for several important reasons:
Reason #1: No risk of liner bulging (refer to FAQ 6)
Reason #2: Direct coverage of the complete carbon steel surface of a compartment (refer to FAQ 7)
Reason #3: A vacuum system is less prone to clogging (refer to FAQ 9)
Reason #4: A vacuum system does not restrict the leaking flow and does not built-up pressure or introduces risks for backflow (refer to FAQ 10)
Reason #5: A vacuum system also works when there is only one leak detection hole in a liner compartment (refer to FAQ 11)
Reason #6 is: A vacuum system also works when there are clogged grooves or no grooves.
But why is that ?
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We recommend a vacuum based leak detection system for several reasons:
Reason #3: A vacuum system is less prone to clogging.
In case of a liner leak and operating a vacuum system, the vacuum pump of the leak detection system will pull the leaking ammonia to the ammonia analyser. After the leak detection circuit in which the leak occurs has been determined, one is able to dilute the leak in this line with air via the vacuum pump by opening the atmospheric ball valve and in that way one dilutes the leaking fluid and reduces (eliminates) the risk for clogging!
On the 25th of March, AmmoniaKnowHow.com will hold a webinar to discuss corrosion issues in ammonia and urea plants. Industry experts and specialists will share their experience. Incidents and case studies will be presented together with the latest technologies for corrosion prevention and mitigation. AmmoniaKnowHow.com webinars are an opportunity for participants to get together in an interactive setting to examine issues related to operation and maintenance of ammonia and urea plants.
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UreaKnowHow.com has reached the impressive milestone of 2000 Round Table discussions. 2000 active Round Table discussion with totally more than 9500 posts or an average of 5 posts per discussion and 2-3 new posts per day. This means everybody who posts a question, for sure will get a reply making the UreaKnowHow.com Round Tables a very valuable information source and place to share experiences.
We thank all participants for their valuable contributions and support and like to highlight and thank very much the 10 most active participants:...Click here to read more
High pressure urea equipment consists of a carbon steel pressure bearing wall, which is protected against corrosion by a protective stainless, titanium or duplex steel layer. This protective layer can be an overlay welding, an explosive cladded layer or a loose liner. Any leak in a loose liner will lead to a dangerous situation in that a large surface of the carbon steel pressure bearing wall underneath the leaking loose liner compartment will be exposed to the extremely corrosive ammonium carbamate. Experience has shown that ammonium carbamate can corrode carbon steels with very high corrosion rates up to 1,000 mm (40 inch) per year.
When talking about active leak detection systems, one can distinguish a pressurized system, in which an inert carrier gas stream flows through the leak detection circuits and a vacuum based system, where one pulls vacuum pressure behind the liner. We recommend a vacuum based leak detection system for several reasons.
But how can a vacuum system distinguish a false indication from for instance an ammonia cloud in the atmosphere from a liner leak ?
This question 7 is in continuation of question 6 in which we started explaining why an active vacuum leak detection system is superior over an active pressurized system. Active leak detection systems can be either a pressurized system, in which an inert carrier gas stream flows through the leak detection circuits most probably only via the machined leak detection grooves present in the carbon steel and a vacuum system, where one pulls vacuum pressure underneath the liner.
We recommend a vacuum based leak detection system for several reasons:
Reason #2: Direct detection of the complete carbon steel surface
Since 100 years ago the industrial production of ammonia began for the widespread agricultural and industrial application. Safety hazards and risks have been identified and for a large extend resolved.
Nowadays ammonia is used more and more as a very efficient hydrogen energy storage, carrier and carbon free fuel. This means that more and more people will get involved with this potentially toxic substance. How will the public and the authorities react?
Are the previously known safety regulations sufficient for the storage / bunkering of ammonia?
We say no, it can be better, more safe and reliable.
We recommend a vacuum based leak detection system for several reasons:
Reason #1: No risk of liner bulging
A first reason is that when using a vacuum system there will be no risk for liner bulging and damage due a to too high pressure in the leak detection system behind the liner. Be aware that the relatively large liner compartments are welded to the carbon steel pressure bearing wall. These large areas allow only a very limited pressure difference between each side of the liner.
Some vendors try to avoid this risk of bulging by switching off the leak detection system when the pressure in the synthesis section is below a certain value. In our view this is not a good solution because...
High pressure urea equipment consist of a heavy carbon steel pressure bearing wall, which is protected against corrosion by a thin corrosion resistant layer; this layer is in the most cases made out of stainless steel or a duplex. This protective layer can be an overlay welding, an explosive cladded layer but is in most cases a loose liner.
Any leak in a loose liner will lead to a dangerous situation because a potentially corrosive fluid can be spread and trapped in the gap between the carbon steel pressure bearing wall and the loose liner. This area will then be exposed to the extremely corrosive ammonium-carbamate.
Real situations have proven that ammonium-carbamate can corrode carbon steels with very high corrosion rates up to 1,000 mm (40 inch) per year. But also stainless steels will show accelerated corrosion because of lack of oxygen. That means that it is an absolute must to have a detection system present that already warns for al leak in an early stage. Then one can only conclude that an active leak detection system is required...
Without water no corrosion.
Jan van der Werf died peacefully Monday morning November 30, 2020 at an age of 76 in his hometown Sittard-Geleen.
With a career of 55 years at Stamicarbon, Jan was enjoying his work with whole his heart. Jan did know where he was talking about, he knew what was urea as he was involved in numerous commissioning and start-up projects. Jan started up one of the first CO2 stripping plants under difficult circumstances in the former DDR, the first PoolCondenser plant in Bangladesh and left his footprint in many other countries like North Korea, Thailand, Romania, USSR, Japan, USA, Myanmar, China, Mexico and Alaska. Jan also worked at several high level management positions in Stamicarbon, always pushing forward innovations and breakthroughs in our industry; amongst many others Safurex® and Full Life Cycle support.
Everywhere we came, people asked how Jan was doing. Jan was open, friendly, flexible and always in a good mood, Jan was really a great manager and colleague, with both feet on the ground, one between his colleagues, his door was always open, Jan was always striving for cooperation and teambuilding. We and we believe many other colleagues owe Jan a lot. Jan was always in to discuss technical issues, strategical topics and life in general, preferably with a pint of beer.
Jan, we will miss you.
We send condolences to Wilma, Guido and Petra and the entire van der Werf family.
In a passive leak detection system an indication of a leak in the liner only shows up when the leak emerges from the leak detection hole. Or, in case the leak detection hole is connected via tubing to for example a bottle with a phenolphthalein solution, when the colour of the liquid in the bottle changes. The detection occurs at a later moment then when the leak occurs in the liner. Time passes (dwell time) between the moment the leak occurred and the moment the leak emerges at the leak detector or when a field operator notifies the leak. The latter case is even worse as the dwell time can be much larger. During that dwell time the risk that the leak detection path gets clogged is realistic. That means that there will be a serious threat to the integrity of the carbon steel pressure bearing wall... Click here to Read more.
AMMO LASER Leak Detection System -
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We are pleased to inform you about all the details via our Frequently Asked Questions
Question #2: When does one need a proper Leak Detection System ?
Click here for the answer
